JPS605004A - 二酸化塩素の製法 - Google Patents
二酸化塩素の製法Info
- Publication number
- JPS605004A JPS605004A JP11682384A JP11682384A JPS605004A JP S605004 A JPS605004 A JP S605004A JP 11682384 A JP11682384 A JP 11682384A JP 11682384 A JP11682384 A JP 11682384A JP S605004 A JPS605004 A JP S605004A
- Authority
- JP
- Japan
- Prior art keywords
- reaction medium
- chlorine dioxide
- normality
- charged
- chloride ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims description 134
- 239000004155 Chlorine dioxide Substances 0.000 title claims description 67
- 235000019398 chlorine dioxide Nutrition 0.000 title claims description 67
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 239000012429 reaction media Substances 0.000 claims description 63
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 54
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 27
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 27
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 15
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 14
- 239000011780 sodium chloride Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000008246 gaseous mixture Substances 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000010924 continuous production Methods 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 description 18
- 229910052801 chlorine Inorganic materials 0.000 description 18
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 17
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- -1 chlorate ions Chemical class 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229940005989 chlorate ion Drugs 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- IYGFDEZBVCNBRU-UHFFFAOYSA-L disodium sulfuric acid sulfate Chemical compound [H+].[H+].[H+].[H+].[Na+].[Na+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IYGFDEZBVCNBRU-UHFFFAOYSA-L 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 2
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010027145 Melanocytic naevus Diseases 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000430111A CA1181224A (en) | 1983-06-10 | 1983-06-10 | High efficiency chlorine dioxide process |
| CA430111 | 1983-06-10 | ||
| CA431677 | 1983-06-30 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1063987A Division JPH01282102A (ja) | 1983-06-10 | 1989-03-17 | 二酸化塩素連続製造方法 |
| JP3245865A Division JPH04367505A (ja) | 1983-06-10 | 1991-09-25 | 二酸化塩素連続製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS605004A true JPS605004A (ja) | 1985-01-11 |
| JPH048363B2 JPH048363B2 (en]) | 1992-02-14 |
Family
ID=4125450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11682384A Granted JPS605004A (ja) | 1983-06-10 | 1984-06-08 | 二酸化塩素の製法 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS605004A (en]) |
| CA (1) | CA1181224A (en]) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04214002A (ja) * | 1990-03-05 | 1992-08-05 | Eka Nobel Ab | 二酸化塩素を製造する方法 |
| JP2013507311A (ja) * | 2009-10-12 | 2013-03-04 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | 二酸化塩素を製造する方法 |
| KR20210011770A (ko) * | 2019-07-23 | 2021-02-02 | 주식회사 클로바이오 | 이산화염소 서방출성 선도유지제와 이의 제조방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52114493A (en) * | 1976-03-19 | 1977-09-26 | Erco Ind Ltd | Manufacturing process for chlorine dioxide by reductio of chlorate |
-
1983
- 1983-06-10 CA CA000430111A patent/CA1181224A/en not_active Expired
-
1984
- 1984-06-08 JP JP11682384A patent/JPS605004A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52114493A (en) * | 1976-03-19 | 1977-09-26 | Erco Ind Ltd | Manufacturing process for chlorine dioxide by reductio of chlorate |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04214002A (ja) * | 1990-03-05 | 1992-08-05 | Eka Nobel Ab | 二酸化塩素を製造する方法 |
| JP2013507311A (ja) * | 2009-10-12 | 2013-03-04 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | 二酸化塩素を製造する方法 |
| KR20210011770A (ko) * | 2019-07-23 | 2021-02-02 | 주식회사 클로바이오 | 이산화염소 서방출성 선도유지제와 이의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH048363B2 (en]) | 1992-02-14 |
| CA1181224A (en) | 1985-01-22 |
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